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Atmospheric-Pressure Conversion of CO(2) to Cyclic Carbonates over Constrained Dinuclear Iron Catalysts

[Image: see text] The conversion of CO(2) and epoxides to cyclic carbonates over a silica-supported di-iron(III) complex having a reduced Robson macrocycle ligand system is shown to proceed at 1 atm and 80 °C, exclusively producing the cis-cyclohexene carbonate from cyclohexene oxide. We examine the...

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Detalles Bibliográficos
Autores principales: Pappuru, Sreenath, Shpasser, Dina, Carmieli, Raanan, Shekhter, Pini, Jentoft, Friederike C., Gazit, Oz M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9301958/
https://www.ncbi.nlm.nih.gov/pubmed/35874206
http://dx.doi.org/10.1021/acsomega.2c02488