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Geometrically Constrained Cationic Low‐Coordinate Tetrylenes: Highly Lewis Acidic σ‐Donor Ligands in Catalytic Systems
A novel non‐innocent ligand class, namely cationic single‐centre ambiphiles, is reported in the phosphine‐functionalised cationic tetrylene Ni(0) complexes, [(PhR)DippENi(PPh(3))(3)](+) (4 a/b (Ge) and 5 (Sn); (PhR)Dipp={[Ph(2)PCH(2)SiR(2)](Dipp)N}(−); R=Ph, (i)Pr; Dipp=2,6‐(i)Pr(2)C(6)H(3)). The in...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9302135/ https://www.ncbi.nlm.nih.gov/pubmed/34818461 http://dx.doi.org/10.1002/anie.202114143 |