Add a Pinch of Tetrel: The Transformation of a Centrosymmetric Metal into a Nonsymmorphic and Chiral Semiconductor

Centrosymmetric skutterudite RhP(3) was converted to a nonsymmorphic and chiral compound RhSi(0.3)P(2.7) (space group P2(1)2(1)2(1)) by means of partial replacement of Si for P. The structure, determined by a combination of X‐ray crystallography and solid state (31)P NMR, exhibits branched polyanion...

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Detalles Bibliográficos
Autores principales: Lee, Shannon J., Viswanathan, Gayatri, Carnahan, Scott L., Harmer, Colin P., Akopov, Georgiy, Rossini, Aaron J., Miller, Gordon J., Kovnir, Kirill
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9302624/
https://www.ncbi.nlm.nih.gov/pubmed/34882857
http://dx.doi.org/10.1002/chem.202104319

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9302624/
https://www.ncbi.nlm.nih.gov/pubmed/34882857
http://dx.doi.org/10.1002/chem.202104319

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