Cargando…
Add a Pinch of Tetrel: The Transformation of a Centrosymmetric Metal into a Nonsymmorphic and Chiral Semiconductor
Centrosymmetric skutterudite RhP(3) was converted to a nonsymmorphic and chiral compound RhSi(0.3)P(2.7) (space group P2(1)2(1)2(1)) by means of partial replacement of Si for P. The structure, determined by a combination of X‐ray crystallography and solid state (31)P NMR, exhibits branched polyanion...
| Autores principales: | , , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9302624/ https://www.ncbi.nlm.nih.gov/pubmed/34882857 http://dx.doi.org/10.1002/chem.202104319 |