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Preparation of Primary and Secondary Dialkylmagnesiums by a Radical I/Mg‐Exchange Reaction Using sBu(2)Mg in Toluene
The treatment of primary or secondary alkyl iodides with sBu(2)Mg in toluene (25–40 °C, 2–4 h) provided dialkylmagnesiums that underwent various reactions with aldehydes, ketones, acid chlorides or allylic bromides. 3‐Substituted secondary cyclohexyl iodides led to all‐cis‐3‐cyclohexylmagnesium reag...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9302629/ https://www.ncbi.nlm.nih.gov/pubmed/35044040 http://dx.doi.org/10.1002/anie.202116625 |