Cargando…

Preparation of Primary and Secondary Dialkylmagnesiums by a Radical I/Mg‐Exchange Reaction Using sBu(2)Mg in Toluene

The treatment of primary or secondary alkyl iodides with sBu(2)Mg in toluene (25–40 °C, 2–4 h) provided dialkylmagnesiums that underwent various reactions with aldehydes, ketones, acid chlorides or allylic bromides. 3‐Substituted secondary cyclohexyl iodides led to all‐cis‐3‐cyclohexylmagnesium reag...

Descripción completa

Detalles Bibliográficos
Autores principales:	Sunagatullina, Alisa S., Lutter, Ferdinand H., Knochel, Paul
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9302629/ https://www.ncbi.nlm.nih.gov/pubmed/35044040 http://dx.doi.org/10.1002/anie.202116625

Ejemplares similares

Directed regioselective ortho,ortho′-magnesiations of aromatics and heterocycles using sBu(2)Mg in toluene
por: Hess, Andreas, et al.
Publicado: (2021)

Kinetics of the Toluene Reaction with OH Radical
por: Zhang, Rui Ming, et al.
Publicado: (2019)

Crystal structure of [tBuMgCl](2)[MgCl(2)(Et(2)O)(2)](2)
por: Metzler, Maurice, et al.
Publicado: (2023)

FRAMEWORK FOR SYSTEMATIC IDENTIFICATION OF ETHICAL ASPECTS OF HEALTHCARE TECHNOLOGIES: THE SBU APPROACH
por: Heintz, Emelie, et al.
Publicado: (2015)

A combined experimental and computational study on the reaction of fluoroarenes with Mg–Mg, Mg–Zn, Mg–Al and Al–Zn bonds
por: Bakewell, Clare, et al.
Publicado: (2018)

Catalytic characteristics of a Ni–MgO/HZSM-5 catalyst for steam reforming of toluene
por: Wu, Wei, et al.
Publicado: (2020)

Selective Functionalization of Tetrathiafulvalene Using Mg- and Zn-TMP-Bases: Preparation of Mono-, Di-, Tri-, and Tetrasubstituted Derivatives
por: Nafe, Julia, et al.
Publicado: (2015)

Exploring the Island of Inversion with the d ($^{30}$Mg, p) $^{31}$Mg reaction
por: Bildstein, Vinzenz
Publicado: (2013)

Cobalt-catalyzed acylation-reactions of (hetero)arylzinc pivalates with thiopyridyl ester derivatives
por: Lutter, Ferdinand H., et al.
Publicado: (2019)

Paddlewheel SBU based Zn MOFs: Syntheses, Structural Diversity, and CO(2) Adsorption Properties
por: Lin, Ting-Ru, et al.
Publicado: (2018)

Quantum dynamics studies of isotope effects in the Mg(+)(3p) + HD → MgH(+)/MgD(+) + D/H insertion reaction
por: Mao, Ye, et al.
Publicado: (2020)

Fusion reactions at the Coulomb barrier with neutron-rich Mg isotopes
por: Reiter, P, et al.
Publicado: (2002)

Recent Advances of the Halogen–Zinc Exchange Reaction
por: Balkenhohl, Moritz, et al.
Publicado: (2020)

Design and Preparation of CNTs/Mg Layered Composites
por: Zhang, Xiao, et al.
Publicado: (2022)

Second brazilian consensus on the treatment of advanced prostate cancer: a SBOC-SBU-SBRT panel review
por: Sasse, Andre Deeke, et al.
Publicado: (2019)

Clinical outcome measures following plasma exchange for MG exacerbation
por: Raja, Shruti M., et al.
Publicado: (2019)

Nuclear Shell Evolution in the Island of Inversion Studied via the $^{28}$Mg(t,$^{30}$Mg)p reaction
por: Muecher, Dennis
Publicado: (2017)

Measurement of the $^{24}Mg(p,t)^{22}Mg$ reaction for the states near the $^{21}Na+p$ threshold
por: Michimasa, S, et al.
Publicado: (2002)

Nuclear Shell Evolution in the Island of Inversion Studied via the $^{28}$Mg(t,$^{30}$Mg)p reaction
por: Mücher, Dennis, et al.
Publicado: (2016)

Myasthenia gravis: MuSK MG, late-onset MG and ocular MG
por: Deymeer, Feza
Publicado: (2020)

CrossTalk opposing view: CNNM proteins are not Na(+)/Mg(2+) exchangers but Mg(2+) transport regulators playing a central role in transepithelial Mg(2+) (re)absorption
por: Arjona, Francisco J., et al.
Publicado: (2018)

Preparation of Polyfunctional Biaryl Derivatives by Cyclolanthanation of 2‐Bromobiaryls and Heterocyclic Analogues Using nBu(2)LaCl⋅4 LiCl
por: Wei, Baosheng, et al.
Publicado: (2019)

Plasma-Catalytic CO(2) Reforming of Toluene over Hydrotalcite-Derived NiFe/(Mg, Al)O(x) Catalysts
por: Liu, Lina, et al.
Publicado: (2023)

Quadrupole Moments of $^{29}$Mg and $^{33}$Mg
por: Yordanov, Deyan Todorov, et al.
Publicado: (2019)

Preparation and Characterization of Nanostructured Hollow MgO Spheres
por: Han, Jishuo, et al.
Publicado: (2019)

The $d$($^{30}$Mg,$p$)$^{31}$Mg reaction: Probing single-particle behaviour within the “island of inversion”
por: Sharp, DK, et al.
Publicado: (2020)

Effects of Reactive MgO on the Reaction Process of Geopolymer
por: Li, Zhaoheng, et al.
Publicado: (2019)

Preparation and Characterization of Novel 5Mg(OH)(2)·MgSO(4)·7H(2)O Whiskers
por: Ning, Xinkuang, et al.
Publicado: (2022)

Evaluation of Mg Compounds as Coating Materials in Mg Batteries
por: Chen, Tina, et al.
Publicado: (2019)

Coulomb excitation of (31)Mg
por: Seidlitz, M, et al.
Publicado: (2011)

Experimentally Observed Nucleation and Growth Behavior of Mg/MgH(2) during De/Hydrogenation of MgH(2)/Mg: A Review
por: Lyu, Jinzhe, et al.
Publicado: (2022)

Dietary Mg(2+) Intake and the Na(+)/Mg(2+) Exchanger SLC41A1 Influence Components of Mitochondrial Energetics in Murine Cardiomyocytes
por: Tatarkova, Zuzana, et al.
Publicado: (2020)

Analgesic effect of oral paracetamol 1000 mg/ibuprofen 400 mg, paracetamol 1000 mg/codeine 60 mg, paracetamol 1000 mg/ibuprofen 400 mg/codeine 60 mg, or placebo on acute postoperative pain: a single-dose, randomized, and double-blind study
por: Lyngstad, Gaute, et al.
Publicado: (2023)

Solid-State Reaction Synthesis of MgAl(2)O(4) Spinel from MgO–Al(2)O(3) Composite Particles Prepared via Electrostatic Adsorption
por: Tran, Anh-Tu, et al.
Publicado: (2023)

The Influence of MgH(2) on the Assessment of Electrochemical Data to Predict the Degradation Rate of Mg and Mg Alloys
por: Mueller, Wolf-Dieter, et al.
Publicado: (2014)

Preparation and Characterization of MgO-Modified Rice Straw Biochars
por: Qin, Xianxian, et al.
Publicado: (2020)

Reinvestigation of the Deceptively Simple Reaction of Toluene with OH and the Fate of the Benzyl Radical: The “Hidden” Routes to Cresols and Benzaldehyde
por: Salta, Zoi, et al.
Publicado: (2020)

Fabrication of Hydrogen Boride Thin Film by Ion Exchange in MgB(2)
por: Hirabayashi, T., et al.
Publicado: (2021)

Cardiovascular effect of dental anesthesia with articaine (40 mg with epinefrine 0,5 mg % and 40 mg with epinefrine 1 mg%) versus mepivacaine (30mg and 20 mg with epinefrine 1 mg%) in medically compromised cardiac patients: A cross-over, randomized, single blinded study
por: Torres-Lagares, Daniel, et al.
Publicado: (2012)

A comparison of preference for and efficacy of tablet formulations of sumatriptan (50 mg and 100 mg), naratriptan (2.5 mg), rizatriptan (10 mg), and zolmitriptan (2.5 mg) in the acute treatment of migraine
por: Dahlöf, Carl, et al.
Publicado: (2004)

Cannot write session to /tmp/vufind_sessions/sess_tnqpuovpte40o1m9ois334g8l7