Polyyne [3]Rotaxanes: Synthesis via Dicobalt Carbonyl Complexes and Enhanced Stability

New strategies for synthesizing polyyne polyrotaxanes are being developed as an approach to stable carbyne “insulated molecular wires”. Here we report an active metal template route to polyyne [3]rotaxanes, using dicobalt carbonyl masked alkyne equivalents. We synthesized two [3]rotaxanes, both with...

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Detalles Bibliográficos
Autores principales: Patrick, Connor W., Woods, Joseph F., Gawel, Przemyslaw, Otteson, Claire E., Thompson, Amber L., Claridge, Tim D. W., Jasti, Ramesh, Anderson, Harry L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9302669/
https://www.ncbi.nlm.nih.gov/pubmed/34995402
http://dx.doi.org/10.1002/anie.202116897

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9302669/
https://www.ncbi.nlm.nih.gov/pubmed/34995402
http://dx.doi.org/10.1002/anie.202116897

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