Dominance of Cyclobutadienyl Over Cyclopentadienyl in the Crystal Field Splitting in Dysprosium Single‐Molecule Magnets

Replacing a monoanionic cyclopentadienyl (Cp) ligand in dysprosium single‐molecule magnets (SMMs) with a dianionic cyclobutadienyl (Cb) ligand in the sandwich complexes [(η(4)‐Cb′′′′)Dy(η(5)‐C(5)Me(4) ( t )Bu)(BH(4))](−) (1), [(η(4)‐Cb′′′′)Dy(η(8)‐Pn(†))K(THF)] (2) and [(η(4)‐Cb′′′′)Dy(η(8)‐Pn(†))](...

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Detalles Bibliográficos
Autores principales: Durrant, James P., Day, Benjamin M., Tang, Jinkui, Mansikkamäki, Akseli, Layfield, Richard A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9302998/
https://www.ncbi.nlm.nih.gov/pubmed/35108431
http://dx.doi.org/10.1002/anie.202200525

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9302998/
https://www.ncbi.nlm.nih.gov/pubmed/35108431
http://dx.doi.org/10.1002/anie.202200525

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