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Dominance of Cyclobutadienyl Over Cyclopentadienyl in the Crystal Field Splitting in Dysprosium Single‐Molecule Magnets
Replacing a monoanionic cyclopentadienyl (Cp) ligand in dysprosium single‐molecule magnets (SMMs) with a dianionic cyclobutadienyl (Cb) ligand in the sandwich complexes [(η(4)‐Cb′′′′)Dy(η(5)‐C(5)Me(4) ( t )Bu)(BH(4))](−) (1), [(η(4)‐Cb′′′′)Dy(η(8)‐Pn(†))K(THF)] (2) and [(η(4)‐Cb′′′′)Dy(η(8)‐Pn(†))](...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9302998/ https://www.ncbi.nlm.nih.gov/pubmed/35108431 http://dx.doi.org/10.1002/anie.202200525 |