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Experiment and Theory Clarify: Sc(+) Receives One Oxygen Atom from SO(2) to Form ScO(+), which Proves to be a Catalyst for the Hidden Oxygen‐Exchange with SO(2)

Using Fourier‐transform ion cyclotron resonance mass spectrometry, it was experimentally determined that Sc(+) in the highly diluted gas phase reacts with SO(2) to form ScO(+) and SO. By (18)O labeling, ScO(+) was shown to play the role of a catalyst when further reacting with SO(2) in a Mars‐van Kr...

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Detalles Bibliográficos
Autores principales: Mercero, Jose M., Rezabal, Elixabete, Ugalde, Jesus M., Weiske, Thomas, Li, Jilai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303259/
https://www.ncbi.nlm.nih.gov/pubmed/34942051
http://dx.doi.org/10.1002/cphc.202100773