Catalytic Asymmetric Additions of Enol Silanes to In Situ Generated Cyclic, Aliphatic N‐Acyliminium Ions

Strong and confined imidodiphosphorimidate (IDPi) catalysts enable highly enantioselective substitutions of cyclic, aliphatic hemiaminal ethers with enol silanes. 2‐Substituted pyrrolidines, piperidines, and azepanes are obtained with high enantioselectivities, and the method displays a broad tolera...

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Detalles Bibliográficos
Autores principales: Grossmann, Oleg, Maji, Rajat, Aukland, Miles H., Lee, Sunggi, List, Benjamin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303265/
https://www.ncbi.nlm.nih.gov/pubmed/34897932
http://dx.doi.org/10.1002/anie.202115036

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303265/
https://www.ncbi.nlm.nih.gov/pubmed/34897932
http://dx.doi.org/10.1002/anie.202115036

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