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Strengthening of the C−F Bond in Fumaryl Fluoride with Superacids

The reaction of fumaryl fluoride with the superacidic solutions XF/MF(5) (X=H, D; M=As, Sb) results in the formation of the monoprotonated and diprotonated species, dependent on the stoichiometric ratio of the Lewis acid to fumaryl fluoride. The salts [C(4)H(3)F(2)O(2)](+)[MF(6)](−) (M=As, Sb) and [...

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Detalles Bibliográficos
Autores principales: Bayer, Marie C., Kremser, Christoph, Jessen, Christoph, Nitzer, Alexander, Kornath, Andreas J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303274/
https://www.ncbi.nlm.nih.gov/pubmed/35081268
http://dx.doi.org/10.1002/chem.202104422