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Strengthening of the C−F Bond in Fumaryl Fluoride with Superacids
The reaction of fumaryl fluoride with the superacidic solutions XF/MF(5) (X=H, D; M=As, Sb) results in the formation of the monoprotonated and diprotonated species, dependent on the stoichiometric ratio of the Lewis acid to fumaryl fluoride. The salts [C(4)H(3)F(2)O(2)](+)[MF(6)](−) (M=As, Sb) and [...
Autores principales: | Bayer, Marie C., Kremser, Christoph, Jessen, Christoph, Nitzer, Alexander, Kornath, Andreas J. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303274/ https://www.ncbi.nlm.nih.gov/pubmed/35081268 http://dx.doi.org/10.1002/chem.202104422 |
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