Piers′ Borane‐Induced Tetramerization of Arylacetylenes

We herein report that the reaction of Piers′ borane, i. e. HB(C(6)F(5))(2), with an excess of arylacetylenes at room temperature leads to tetramerization of the acetylene and the diastereoselective formation of boryl‐substituted tetra‐aryl‐tetrahydropentalenes. The reaction mechanism was investigate...

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Detalles Bibliográficos
Autores principales: Hasenbeck, Max, Müller, Tizian, Averdunk, Arthur, Becker, Jonathan, Gellrich, Urs
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303334/
https://www.ncbi.nlm.nih.gov/pubmed/34882876
http://dx.doi.org/10.1002/chem.202104254

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303334/
https://www.ncbi.nlm.nih.gov/pubmed/34882876
http://dx.doi.org/10.1002/chem.202104254

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