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Piers′ Borane‐Induced Tetramerization of Arylacetylenes
We herein report that the reaction of Piers′ borane, i. e. HB(C(6)F(5))(2), with an excess of arylacetylenes at room temperature leads to tetramerization of the acetylene and the diastereoselective formation of boryl‐substituted tetra‐aryl‐tetrahydropentalenes. The reaction mechanism was investigate...
Autores principales: | Hasenbeck, Max, Müller, Tizian, Averdunk, Arthur, Becker, Jonathan, Gellrich, Urs |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303334/ https://www.ncbi.nlm.nih.gov/pubmed/34882876 http://dx.doi.org/10.1002/chem.202104254 |
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