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Sterically Crowded Tris(2‐(trimethylsilyl)phenyl)phosphine – Is it Still a Ligand?

Tris(2‐(trimethylsilyl)phenyl)phosphine, P(o‐TMSC(6)H(4))(3), was synthesised and characterised in solution and in the solid state. The large steric bulk prevents most reactions of the phosphorus donor and makes the compound air stable both in the solid state as well as in solution. This shielded ph...

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Detalles Bibliográficos
Autores principales: Gildenast, Hans, Garg, Felix, Englert, Ulli
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303349/
https://www.ncbi.nlm.nih.gov/pubmed/34856017
http://dx.doi.org/10.1002/chem.202103555