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Sterically Crowded Tris(2‐(trimethylsilyl)phenyl)phosphine – Is it Still a Ligand?
Tris(2‐(trimethylsilyl)phenyl)phosphine, P(o‐TMSC(6)H(4))(3), was synthesised and characterised in solution and in the solid state. The large steric bulk prevents most reactions of the phosphorus donor and makes the compound air stable both in the solid state as well as in solution. This shielded ph...
Autores principales: | Gildenast, Hans, Garg, Felix, Englert, Ulli |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303349/ https://www.ncbi.nlm.nih.gov/pubmed/34856017 http://dx.doi.org/10.1002/chem.202103555 |
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