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Borane Adducts of Aromatic Phosphorus Heterocycles: Synthesis, Crystallographic Characterization and Reactivity of a Phosphinine‐B(C(6)F(5))(3) Lewis Pair

A phosphinine‐borane adduct of a Me(3)Si‐functionalized phosphinine and the Lewis acid B(C(6)F(5))(3) has been synthesized and characterized crystallographically for the first time. The reaction strongly depends on the nature of the substituents in the α‐position of the phosphorus heterocycle. In co...

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Detalles Bibliográficos
Autores principales: Lin, Jinxiong, Wossidlo., Friedrich, Coles, Nathan T., Weber, Manuela, Steinhauer, Simon, Böttcher, Tobias, Müller, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303379/
https://www.ncbi.nlm.nih.gov/pubmed/34967480
http://dx.doi.org/10.1002/chem.202104135