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Practical approaches to labelling terminal alkynes with deuterium

Base catalysed exchange with sodium hydroxide, calcium oxide or N,N,N,N‐tetramethylguanidine in deuterium oxide is a viable procedure for the preparation of terminally deuterated alkynes for those alkynes stable to strong base. The use of silver perchlorate as a catalyst is an alternative practical...

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Detalles Bibliográficos
Autores principales: Chan, Melanie Y. T., Anwar, Arbab, Lockley, William J. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303397/
https://www.ncbi.nlm.nih.gov/pubmed/35067956
http://dx.doi.org/10.1002/jlcr.3963