Stereoselective Synthesis of Tertiary Allylic Amines by Titanium‐Catalyzed Hydroaminoalkylation of Alkynes with Tertiary Amines

Intermolecular hydroaminoalkylation reactions of symmetrical and unsymmetrical alkynes with tertiary amines take place in the presence of catalytic amounts of TiBn(4), Ph(3)C[B(C(6)F(5))(4)], and a sterically demanding aminopyridinato ligand precursor. The resulting products, synthetically and pharm...

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Detalles Bibliográficos
Autores principales: Kaper, Tobias, Geik, Dennis, Fornfeist, Felix, Schmidtmann, Marc, Doye, Sven
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303398/
https://www.ncbi.nlm.nih.gov/pubmed/34936144
http://dx.doi.org/10.1002/chem.202103931

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303398/
https://www.ncbi.nlm.nih.gov/pubmed/34936144
http://dx.doi.org/10.1002/chem.202103931

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