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Stereoselective Synthesis of Tertiary Allylic Amines by Titanium‐Catalyzed Hydroaminoalkylation of Alkynes with Tertiary Amines
Intermolecular hydroaminoalkylation reactions of symmetrical and unsymmetrical alkynes with tertiary amines take place in the presence of catalytic amounts of TiBn(4), Ph(3)C[B(C(6)F(5))(4)], and a sterically demanding aminopyridinato ligand precursor. The resulting products, synthetically and pharm...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303398/ https://www.ncbi.nlm.nih.gov/pubmed/34936144 http://dx.doi.org/10.1002/chem.202103931 |