Formation and Reactivity of a Hexahydridosilicate [SiH(6)](2−) Coordinated by a Macrocycle‐Supported Strontium Cation

The cationic benzyl complex [(Me(4)TACD)Sr(CH(2)Ph)][A] (Me(4)TACD=1,4,7,10‐tetramethyltetraazacyclododecane; A=B(C(6)H(3)‐3,5‐Me(2))(4)) reacted with two equivalents of phenylsilane to give the bridging hexahydridosilicate complex [(Me(4)TACD)(2)Sr(2)(thf)(4)(μ‐κ(3) : κ(3)‐SiH(6))][A](2) (3 a). Rap...

Descripción completa

Detalles Bibliográficos
Autores principales: Höllerhage, Thomas, Ghana, Priyabrata, Spaniol, Thomas P., Carpentier, Ambre, Maron, Laurent, Englert, Ulli, Okuda, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303417/
https://www.ncbi.nlm.nih.gov/pubmed/34874085
http://dx.doi.org/10.1002/anie.202115379

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303417/
https://www.ncbi.nlm.nih.gov/pubmed/34874085
http://dx.doi.org/10.1002/anie.202115379

Ejemplares similares