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Formation and Reactivity of a Hexahydridosilicate [SiH(6)](2−) Coordinated by a Macrocycle‐Supported Strontium Cation
The cationic benzyl complex [(Me(4)TACD)Sr(CH(2)Ph)][A] (Me(4)TACD=1,4,7,10‐tetramethyltetraazacyclododecane; A=B(C(6)H(3)‐3,5‐Me(2))(4)) reacted with two equivalents of phenylsilane to give the bridging hexahydridosilicate complex [(Me(4)TACD)(2)Sr(2)(thf)(4)(μ‐κ(3) : κ(3)‐SiH(6))][A](2) (3 a). Rap...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303417/ https://www.ncbi.nlm.nih.gov/pubmed/34874085 http://dx.doi.org/10.1002/anie.202115379 |