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Guest‐Dependent Isomer Convergence of a Permanently Fluxional Coordination Cage

A fluxional bis‐monodentate ligand, based on the archetypal shape‐shifting molecule bullvalene, self‐assembles with M(2+) (M=Pd(2+) or Pt(2+)) to produce a highly complex ensemble of permanently fluxional coordination cages. Metal‐mediated self‐assembly selects for an M(2)L(4) architecture while mai...

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Detalles Bibliográficos
Autores principales: Birvé, André P., Patel, Harshal D., Price, Jason R., Bloch, Witold M., Fallon, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303423/
https://www.ncbi.nlm.nih.gov/pubmed/34854191
http://dx.doi.org/10.1002/anie.202115468