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Competition for Hydride Between Silicon and Boron: Synthesis and Characterization of a Hydroborane‐Stabilized Silylium Ion

Potent main‐group Lewis acids are capable of activating element‐hydrogen bonds. To probe the rivalry for hydride between silylium‐ and borenium‐ion centers, a neutral precursor with the hydrosilane and hydroborane units in close proximity on a naphthalene‐1,8‐diyl platform was designed. Abstraction...

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Detalles Bibliográficos
Autores principales: Gao, Haopeng, Müller, Robert, Irran, Elisabeth, Klare, Hendrik F. T., Kaupp, Martin, Oestreich, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303568/
https://www.ncbi.nlm.nih.gov/pubmed/34918852
http://dx.doi.org/10.1002/chem.202104464