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Competition for Hydride Between Silicon and Boron: Synthesis and Characterization of a Hydroborane‐Stabilized Silylium Ion
Potent main‐group Lewis acids are capable of activating element‐hydrogen bonds. To probe the rivalry for hydride between silylium‐ and borenium‐ion centers, a neutral precursor with the hydrosilane and hydroborane units in close proximity on a naphthalene‐1,8‐diyl platform was designed. Abstraction...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303568/ https://www.ncbi.nlm.nih.gov/pubmed/34918852 http://dx.doi.org/10.1002/chem.202104464 |