A Persistent Phosphanyl‐Substituted Thioketyl Radical Anion

Alkali metal salts, M(+)[Ter(iPr)P−C(=S)−P(iPr)(2)S](.−) (M=Na, K; 2_M; Ter=2,6‐bis‐(2,4,6‐trimethylphenyl)phenyl) containing a room‐temperature‐stable thioketyl radical anion were obtained by reduction of the thioketone precursor, Ter(iPr)P−C(=S)−P(iPr)(2)S (1), with alkali metals (Na, K). Single‐c...

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Detalles Bibliográficos
Autores principales: Szych, Lilian Sophie, Pilopp, Yannic, Bresien, Jonas, Villinger, Alexander, Rabeah, Jabor, Schulz, Axel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303638/
https://www.ncbi.nlm.nih.gov/pubmed/34843637
http://dx.doi.org/10.1002/anie.202114792

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303638/
https://www.ncbi.nlm.nih.gov/pubmed/34843637
http://dx.doi.org/10.1002/anie.202114792

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