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A Persistent Phosphanyl‐Substituted Thioketyl Radical Anion
Alkali metal salts, M(+)[Ter(iPr)P−C(=S)−P(iPr)(2)S](.−) (M=Na, K; 2_M; Ter=2,6‐bis‐(2,4,6‐trimethylphenyl)phenyl) containing a room‐temperature‐stable thioketyl radical anion were obtained by reduction of the thioketone precursor, Ter(iPr)P−C(=S)−P(iPr)(2)S (1), with alkali metals (Na, K). Single‐c...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303638/ https://www.ncbi.nlm.nih.gov/pubmed/34843637 http://dx.doi.org/10.1002/anie.202114792 |