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C(sp(3))−H Arylation Promoted by a Heterogeneous Palladium‐N‐Heterocyclic Carbene Complex in Batch and Continuous Flow

A heterogeneous reusable palladium(II)‐bis(N‐heterocyclic carbene) catalyst was prepared and shown to catalyze the intramolecular C(sp(3))−H activation/cyclization of N‐alkyl‐2‐bromoanilines furnishing indolines. This new catalytic system was based on a bis‐imidazolium ligand immobilized on a spaced...

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Detalles Bibliográficos
Autores principales: Ferlin, Francesco, Anastasiou, Ioannis, Salameh, Nihad, Miyakoshi, Takeru, Baudoin, Olivier, Vaccaro, Luigi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303704/
https://www.ncbi.nlm.nih.gov/pubmed/35098689
http://dx.doi.org/10.1002/cssc.202102736