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Incommensurate Phase in Λ‐cobalt (III) Sepulchrate Trinitrate Governed by Highly Competitive N−H⋅⋅⋅O and C−H⋅⋅⋅O Hydrogen Bond Networks
Phase transitions in molecular crystals are often determined by intermolecular interactions. The cage complex of [Co(C(12)H(30)N(8))](3+) ⋅ 3 NO(3) (−) is reported to undergo a disorder‐order phase transition at T (c1) ≈133 K upon cooling. Temperature‐dependent neutron and synchrotron diffraction ex...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303887/ https://www.ncbi.nlm.nih.gov/pubmed/35072296 http://dx.doi.org/10.1002/chem.202104151 |