Anion–π Catalysis Enabled by the Mechanical Bond

We report a series of rotaxane‐based anion–π catalysts in which the mechanical bond between a bipyridine macrocycle and an axle containing an NDI unit is intrinsic to the activity observed, including a [3]rotaxane that catalyses an otherwise disfavoured Michael addition in >60 fold selectivity ov...

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Detalles Bibliográficos
Autores principales: Maynard, John R. J., Galmés, Bartomeu, Stergiou, Athanasios D., Symes, Mark D., Frontera, Antonio, Goldup, Stephen M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303940/
https://www.ncbi.nlm.nih.gov/pubmed/35040543
http://dx.doi.org/10.1002/anie.202115961

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9303940/
https://www.ncbi.nlm.nih.gov/pubmed/35040543
http://dx.doi.org/10.1002/anie.202115961

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