A Brønsted Acidic Gallium Hydride: Facile Interconversion of NNNN‐Macrocycle Supported [Ga(I)](+) and [Ga(III)H](2+)

Protonolysis of [Cp*M] (M=Ga, In, Tl) with [(Me(4)TACD)H][BAr(4) (Me)] (Me(4)TACD=N,N′,N′′,N′′′‐tetramethyl‐1,4,7,10‐tetraazacyclododecane; [BAr(4) (Me)](−)=[B{C(6)H(3)‐3,5‐(CH(3))(2)}(4)](−)) provided monovalent salts [(Me(4)TACD)M][BAr(4) (Me)], whereas [Cp*Al](4) yielded trivalent [(Me(4)TACD)AlH...

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Detalles Bibliográficos
Autores principales: Morris, Louis J., Ghana, Priyabrata, Rajeshkumar, Thayalan, Carpentier, Ambre, Maron, Laurent, Okuda, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9304309/
https://www.ncbi.nlm.nih.gov/pubmed/34932267
http://dx.doi.org/10.1002/anie.202114629

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9304309/
https://www.ncbi.nlm.nih.gov/pubmed/34932267
http://dx.doi.org/10.1002/anie.202114629

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