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Nitrogen Atom Transfer Catalysis by Metallonitrene C−H Insertion: Photocatalytic Amidation of Aldehydes

C−H amination and amidation by catalytic nitrene transfer are well‐established and typically proceed via electrophilic attack of nitrenoid intermediates. In contrast, the insertion of (formal) terminal nitride ligands into C−H bonds is much less developed and catalytic nitrogen atom transfer remains...

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Detalles Bibliográficos
Autores principales: Schmidt‐Räntsch, Till, Verplancke, Hendrik, Lienert, Jonas N., Demeshko, Serhiy, Otte, Matthias, Van Trieste, Gerard P., Reid, Kaleb A., Reibenspies, Joseph H., Powers, David C., Holthausen, Max C., Schneider, Sven
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9305406/
https://www.ncbi.nlm.nih.gov/pubmed/34905281
http://dx.doi.org/10.1002/anie.202115626