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Characterization of Mannosyl Dioxanium Ions in Solution Using Chemical Exchange Saturation Transfer NMR Spectroscopy

The stereoselective introduction of the glycosidic bond remains one of the main challenges in carbohydrate synthesis. Characterizing the reactive intermediates of this reaction is key to develop stereoselective glycosylation reactions. Herein we report the characterization of low‐populated, rapidly...

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Detalles Bibliográficos
Autores principales: de Kleijne, Frank F. J., Elferink, Hidde, Moons, Sam J., White, Paul B., Boltje, Thomas J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9305821/
https://www.ncbi.nlm.nih.gov/pubmed/34519403
http://dx.doi.org/10.1002/anie.202109874