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Master of Chaos and Order: Opposite Microstructures of PCL‐co‐PGA‐co‐PLA Accessible by a Single Catalyst

One catalyst, two reaction set‐ups, three monomers and unlimited macromolecular microstructural designs: The iron guanidine complex [FeCl(2)(TMG5NMe(2)asme)] (1) polymerizes lactide faster than the industrially used Sn(Oct)(2) and shows high activity towards glycolide and ϵ‐caprolactone. Its disting...

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Detalles Bibliográficos
Autores principales: Rittinghaus, Ruth D., Zenner, Johannes, Pich, Andrij, Kol, Moshe, Herres‐Pawlis, Sonja
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9305917/
https://www.ncbi.nlm.nih.gov/pubmed/34984790
http://dx.doi.org/10.1002/anie.202112853