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Master of Chaos and Order: Opposite Microstructures of PCL‐co‐PGA‐co‐PLA Accessible by a Single Catalyst
One catalyst, two reaction set‐ups, three monomers and unlimited macromolecular microstructural designs: The iron guanidine complex [FeCl(2)(TMG5NMe(2)asme)] (1) polymerizes lactide faster than the industrially used Sn(Oct)(2) and shows high activity towards glycolide and ϵ‐caprolactone. Its disting...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9305917/ https://www.ncbi.nlm.nih.gov/pubmed/34984790 http://dx.doi.org/10.1002/anie.202112853 |