Access to a Labile Monomeric Magnesium Radical by Ball‐Milling

In order to isolate a monometallic Mg radical, the precursor (Am)MgI⋅(CAAC) (1) was prepared (Am=tBuC(N‐DIPP)(2), DIPP=2,6‐diisopropylphenyl, CAAC=cyclic (alkyl)(amino)carbene). Reduction of a solution of 1 in toluene with the reducing agent K/KI led to formation of a deep purple complex that rapidl...

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Detalles Bibliográficos
Autores principales: Jędrzkiewicz, Dawid, Mai, Jonathan, Langer, Jens, Mathe, Zachary, Patel, Neha, DeBeer, Serena, Harder, Sjoerd
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9306460/
https://www.ncbi.nlm.nih.gov/pubmed/35108440
http://dx.doi.org/10.1002/anie.202200511

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9306460/
https://www.ncbi.nlm.nih.gov/pubmed/35108440
http://dx.doi.org/10.1002/anie.202200511

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