Cargando…
Access to a Labile Monomeric Magnesium Radical by Ball‐Milling
In order to isolate a monometallic Mg radical, the precursor (Am)MgI⋅(CAAC) (1) was prepared (Am=tBuC(N‐DIPP)(2), DIPP=2,6‐diisopropylphenyl, CAAC=cyclic (alkyl)(amino)carbene). Reduction of a solution of 1 in toluene with the reducing agent K/KI led to formation of a deep purple complex that rapidl...
Autores principales: | Jędrzkiewicz, Dawid, Mai, Jonathan, Langer, Jens, Mathe, Zachary, Patel, Neha, DeBeer, Serena, Harder, Sjoerd |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9306460/ https://www.ncbi.nlm.nih.gov/pubmed/35108440 http://dx.doi.org/10.1002/anie.202200511 |
Ejemplares similares
-
Alkaline‐Earth Metal Mediated Benzene‐to‐Biphenyl Coupling
por: Mai, Jonathan, et al.
Publicado: (2022) -
On the existence of low-valent magnesium–calcium complexes
por: Mai, Jonathan, et al.
Publicado: (2023) -
Effect of additives, ball milling and isotopic exchange in porous magnesium borohydride
por: Heere, Michael, et al.
Publicado: (2018) -
Microstructural Transformation and Hydrogen Generation Performance of Magnesium Scrap Ball Milled with Devarda’s Alloy
por: Buryakovskaya, Olesya A., et al.
Publicado: (2022) -
Enhanced Hydrogen Generation from Magnesium–Aluminum Scrap Ball Milled with Low Melting Point Solder Alloy
por: Buryakovskaya, Olesya A., et al.
Publicado: (2023)