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Selective Para‐C−H Alkynylation of Aniline Derivatives by Pd/S,O‐Ligand Catalysis

Herein, we report a nondirected para‐selective C−H alkynylation of aniline derivatives by a Pd/S,O‐ligand‐based catalyst. The reaction proceeds under mild conditions and is compatible with a variety of substituted anilines. The scalability and further derivatizations of the alkynylated products have...

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Detalles Bibliográficos
Autores principales: Deng, Ke‐Zuan, Jia, Wen‐Liang, Ángeles Fernández‐Ibáñez, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9306564/
https://www.ncbi.nlm.nih.gov/pubmed/34902180
http://dx.doi.org/10.1002/chem.202104107