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Calix[4]pyrrolato Stannate(II): A Tetraamido Tin(II) Dianion and Strong Metal‐Centered σ‐Donor

Anionic, metal‐centered nucleophiles are emerging compounds with unique reactivities. Here, we describe the isolation and full characterization of the first tetraamido tin(II) dianion, its behavior as ligand towards transition metals, and its reactivity as a tin‐centered nucleophile. Experimental va...

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Detalles Bibliográficos
Autores principales: Ruppert, Heiko, Greb, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9306640/
https://www.ncbi.nlm.nih.gov/pubmed/35019214
http://dx.doi.org/10.1002/anie.202116615