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Isolation and Properties of the Long Elusive Deep Blue Soluble [K(3){(N( t )Bu)(3)S}(2)](.) Cage Radical
The reaction of potassium metal with sulfurtriimide S(N( t )Bu)(3) (II) gives the long elusive deep blue cage radical [K( 3 ){(N( t )Bu)( 3 )S}( 2 )](.) (1_K) that crystallizes at −35 °C from toluene solution. The subsequent physical characterization via X‐ray structure analysis, UV/Vis‐, and EPR sp...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9306764/ https://www.ncbi.nlm.nih.gov/pubmed/34905651 http://dx.doi.org/10.1002/anie.202115026 |