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Isolation and Properties of the Long Elusive Deep Blue Soluble [K(3){(N( t )Bu)(3)S}(2)](.) Cage Radical

The reaction of potassium metal with sulfurtriimide S(N( t )Bu)(3) (II) gives the long elusive deep blue cage radical [K( 3 ){(N( t )Bu)( 3 )S}( 2 )](.) (1_K) that crystallizes at −35 °C from toluene solution. The subsequent physical characterization via X‐ray structure analysis, UV/Vis‐, and EPR sp...

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Detalles Bibliográficos
Autores principales: Legendre, Christina M., Stückl, A. Claudia, Sindlinger, Christian P., Herbst‐Irmer, Regine, Stalke, Dietmar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9306764/
https://www.ncbi.nlm.nih.gov/pubmed/34905651
http://dx.doi.org/10.1002/anie.202115026