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Assessing Alkali‐Metal Effects in the Structures and Reactivity of Mixed‐Ligand Alkyl/Alkoxide Alkali‐Metal Magnesiates

Advancing the understanding of using alkali‐metal alkoxides as additives to organomagnesium reagents in Mg−Br exchange reactions, a homologous series of mixed‐ligand alkyl/alkoxide alkali‐metal magnesiates [MMg(CH(2)SiMe(3))(2)(dmem)](2) [dmem=2‐{[2‐(dimethylamino)ethyl]methylamino} ethoxide; M=Li,...

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Detalles Bibliográficos
Autores principales: Judge, Neil R., Bole, Leonie J., Hevia, Eva
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9306829/
https://www.ncbi.nlm.nih.gov/pubmed/34939701
http://dx.doi.org/10.1002/chem.202104164