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Proton or Carbene Transfer? On the Dark and Light Reaction of Diazoalkanes with Alcohols

The formal alkylation reaction of OH groups with diazoalkanes under catalyst‐free reaction conditions finds broad application in organic synthesis. However, even today, this reaction is mainly limited to the use of diazomethane as reaction partner. In this combined experimental and theoretical study...

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Detalles Bibliográficos
Autores principales: Empel, Claire, Pei, Chao, He, Feifei, Jana, Sripati, Koenigs, Rene M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9306865/
https://www.ncbi.nlm.nih.gov/pubmed/35060651
http://dx.doi.org/10.1002/chem.202104397