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Proton or Carbene Transfer? On the Dark and Light Reaction of Diazoalkanes with Alcohols
The formal alkylation reaction of OH groups with diazoalkanes under catalyst‐free reaction conditions finds broad application in organic synthesis. However, even today, this reaction is mainly limited to the use of diazomethane as reaction partner. In this combined experimental and theoretical study...
Autores principales: | Empel, Claire, Pei, Chao, He, Feifei, Jana, Sripati, Koenigs, Rene M. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9306865/ https://www.ncbi.nlm.nih.gov/pubmed/35060651 http://dx.doi.org/10.1002/chem.202104397 |
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