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The Apparently Unreactive Substrate Facilitates the Electron Transfer for Dioxygen Activation in Rieske Dioxygenases

Rieske dioxygenases belong to the non‐heme iron family of oxygenases and catalyze important cis‐dihydroxylation as well as O‐/N‐dealkylation and oxidative cyclization reactions for a wide range of substrates. The lack of substrate coordination at the non‐heme ferrous iron center, however, makes it p...

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Detalles Bibliográficos
Autores principales: Csizi, Katja‐Sophia, Eckert, Lina, Brunken, Christoph, Hofstetter, Thomas B., Reiher, Markus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9306888/
https://www.ncbi.nlm.nih.gov/pubmed/35072969
http://dx.doi.org/10.1002/chem.202103937