Potassium Aluminyl Promoted Carbonylation of Ethene

The potassium aluminyl [K{Al(NON(Dipp))}](2) ([NON(Dipp)](2−)=[O{SiMe(2)NDipp}(2)](2−), Dipp=2,6‐iPr(2)C(6)H(3)) activates ethene towards carbonylation with CO under mild conditions. An isolated bis‐aluminacyclopropane compound reacted with CO via carbonylation of an Al−C bond, followed by an intram...

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Detalles Bibliográficos
Autores principales: Evans, Matthew J., Neale, Samuel E., Anker, Mathew D., McMullin, Claire L., Coles, Martyn P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9307019/
https://www.ncbi.nlm.nih.gov/pubmed/35166007
http://dx.doi.org/10.1002/anie.202117396

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9307019/
https://www.ncbi.nlm.nih.gov/pubmed/35166007
http://dx.doi.org/10.1002/anie.202117396

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