Quantitative Assessment of Ligand Substituent Effects on σ‐ and π‐Contributions to Fe−N Bonds in Spin Crossover Fe(II) Complexes

The effect of para‐substituent X on the electronic structure of sixteen tridentate 4‐X‐(2,6‐di(pyrazol‐1‐yl))‐pyridine (bpp(X) ) ligands and the corresponding solution spin crossover [Fe(II)(bpp(X) )(2)](2+) complexes is analysed further, to supply quantitative insights into the effect of X on the σ...

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Detalles Bibliográficos
Autores principales: Bondì, Luca, Garden, Anna L., Totti, Federico, Jerabek, Paul, Brooker, Sally
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9310619/
https://www.ncbi.nlm.nih.gov/pubmed/35224791
http://dx.doi.org/10.1002/chem.202104314

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9310619/
https://www.ncbi.nlm.nih.gov/pubmed/35224791
http://dx.doi.org/10.1002/chem.202104314

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