Sigma/pi Bonding Preferences of Solvated Alkali‐Metal Cations to Ditopic Arylmethyl Anions

Arylmethyl anions allow alkali‐metals to bind in a σ‐fashion to the lateral carbanionic centre or a π‐fashion to the aryl ring or in between these extremities, with the trend towards π bonding increasing on descending group 1. Here we review known alkali metal structures of diphenylmethane, fluorene...

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Detalles Bibliográficos
Autores principales: Rae, Annabel, Byrne, Keelan M., Brown, Scott A., Kennedy, Alan R., Krämer, Tobias, Mulvey, Robert E., Robertson, Stuart D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9310864/
https://www.ncbi.nlm.nih.gov/pubmed/35170823
http://dx.doi.org/10.1002/chem.202104260

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9310864/
https://www.ncbi.nlm.nih.gov/pubmed/35170823
http://dx.doi.org/10.1002/chem.202104260

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