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Sigma/pi Bonding Preferences of Solvated Alkali‐Metal Cations to Ditopic Arylmethyl Anions
Arylmethyl anions allow alkali‐metals to bind in a σ‐fashion to the lateral carbanionic centre or a π‐fashion to the aryl ring or in between these extremities, with the trend towards π bonding increasing on descending group 1. Here we review known alkali metal structures of diphenylmethane, fluorene...
Autores principales: | Rae, Annabel, Byrne, Keelan M., Brown, Scott A., Kennedy, Alan R., Krämer, Tobias, Mulvey, Robert E., Robertson, Stuart D. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9310864/ https://www.ncbi.nlm.nih.gov/pubmed/35170823 http://dx.doi.org/10.1002/chem.202104260 |
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