Insights into the Electronic Structure of a U(IV) Amido and U(V) Imido Complex

Reaction of the N‐heterocylic carbene ligand (i)PrIm (L(1)) and lithium bis(trimethylsilyl)amide (TMSA) as a base with UCl(4) resulted in U(IV) and U(V) complexes. Uranium's +V oxidation state in (HL(1))(2)[U(V)(TMSI)Cl(5)] (TMSI=trimethylsilylimido) (2) was confirmed by HERFD‐XANES measurement...

Descripción completa

Detalles Bibliográficos
Autores principales: Köhler, Luisa, Patzschke, Michael, Bauters, Stephen, Vitova, Tonya, Butorin, Sergei M., Kvashnina, Kristina O., Schmidt, Moritz, Stumpf, Thorsten, März, Juliane
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9310906/
https://www.ncbi.nlm.nih.gov/pubmed/35179271
http://dx.doi.org/10.1002/chem.202200119

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9310906/
https://www.ncbi.nlm.nih.gov/pubmed/35179271
http://dx.doi.org/10.1002/chem.202200119

Ejemplares similares